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Oxidation of ethanol over Mn–Ce–O and Mn–Ce–Zr–O complex compounds synthesized by sol–gel method

Paper ID Volume ID Publish Year Pages File Format Full-Text
52576 46877 2007 5 PDF Available
Title
Oxidation of ethanol over Mn–Ce–O and Mn–Ce–Zr–O complex compounds synthesized by sol–gel method
Abstract

The complete oxidation of ethanol was studied over Mn0.1Ce0.9Ox and Mn0.1Ce0.6Zr0.3Ox complex compounds prepared by sol–gel method. Samples were characterized by XRD, BET, EPR and XPS techniques. For fresh samples, the ethanol complete oxidation is easier over Mn0.1Ce0.9Ox than Mn0.1Ce0.6Zr0.3Ox, whereas the order is reversed for aged samples. The stabilizing effect of Zr on Mn–Ce–O is confirmed by BET and XRD. Further, the relationship between catalyst structure and its activity for ethanol total oxidation is investigated by EPR and XPS.

Keywords
Mn–Ce oxide; Mn–Ce–Zr oxide; Automotive exhaust catalyst; Ethanol
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Oxidation of ethanol over Mn–Ce–O and Mn–Ce–Zr–O complex compounds synthesized by sol–gel method
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 8, Issue 11, November 2007, Pages 1743–1747
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
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