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The unique behavior of the catalytic system Pd(OAc)2/N-heterocyclic carbene on the telomerization of isoprene with methanol

Paper ID Volume ID Publish Year Pages File Format Full-Text
52586 46877 2007 5 PDF Available
Title
The unique behavior of the catalytic system Pd(OAc)2/N-heterocyclic carbene on the telomerization of isoprene with methanol
Abstract

The catalytic system Pd(OAc)2/1,3-bis(2,4,6-trimethylphenyl)imidazolium chloride (IMes · HCl) promotes the telomerization of isoprene with methanol resulting in methoxy-dimers with a head-to-head coupling of the isoprene units at unprecedented activity and selectivity. Employing 1,3-bis(2,6-di-i-propylphenyl)-4,5-dihydroimidazolium tetrafluoroborate (SIPr · HBF4) instead of IMes · HCl, new sesquiterpenes are obtained by the trimerization of isoprene.

Keywords
Telomerization; Isoprene; N-Heterocyclic carbene; Sesquiterpene; Head-to-head coupling; Palladium catalyst
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The unique behavior of the catalytic system Pd(OAc)2/N-heterocyclic carbene on the telomerization of isoprene with methanol
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 8, Issue 11, November 2007, Pages 1798–1802
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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