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Synergistic role of aluminium in stabilization of mixed metal oxide catalyst for the nitration of aromatic compounds

Paper ID Volume ID Publish Year Pages File Format Full-Text
52607 46878 2006 7 PDF Available
Title
Synergistic role of aluminium in stabilization of mixed metal oxide catalyst for the nitration of aromatic compounds
Abstract

Aluminium stabilized mixed metal oxide of copper and iron serve as an active catalyst for the nitration of benzene in solid–liquid phase reaction, using 69% nitric acid as a nitrating agent. The reaction was carried out with 100% selectivity towards nitro benzene. Various solvents such as, n-hexane, n-heptane, DMC and DCE were employed, DCE was the most effective in removal of water azeotropically in acidic medium, which is the only byproduct formed in the reaction. The activity of the catalyst decreases in the repeated use due to partial leaching.

Keywords
Stabilized; Mixed metal oxide; Nitration; Solid–liquid phase; Nitric acid
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Synergistic role of aluminium in stabilization of mixed metal oxide catalyst for the nitration of aromatic compounds
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 7, Issue 7, July 2006, Pages 443–449
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
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Full-text PDF Download
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