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Room temperature oxidation of alcohols with 1 atm dioxygen and air catalyzed by a novel three-dimensional microporous ruthenium(II,III) 4,4′,4″,4‴-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakisbenzoate tetrafluoroborate

Paper ID Volume ID Publish Year Pages File Format Full-Text
52634 46879 2006 5 PDF Available
Title
Room temperature oxidation of alcohols with 1 atm dioxygen and air catalyzed by a novel three-dimensional microporous ruthenium(II,III) 4,4′,4″,4‴-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakisbenzoate tetrafluoroborate
Abstract

A novel three-dimensional microporous ruthenium (II,III) polymer complex, [Ru2II,III(H2TCPP)]BF4 (1) (H2TCPP = 4,4′,4′,4‴-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis benzoic acid) was synthesized and characterized by elemental analysis, TG/DTA, magnetic susceptibility, FT-IR, diffuse reflectance UV–Vis, ESR, X-ray powder diffraction, BET analysis, and nitrogen and oxygen adsorption measurements. Complex 1 exhibited an effective catalytic performance for the heterogeneous oxidation of various types of alcohols, particularly primary aliphatic alcohols, with molecular oxygen and air without any additives at room temperature.

Keywords
Ruthenium(II,III) carboxylate polymer complex; Porphyrin; Microporous materials; Alcohol oxidation; Molecular oxygen
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Room temperature oxidation of alcohols with 1 atm dioxygen and air catalyzed by a novel three-dimensional microporous ruthenium(II,III) 4,4′,4″,4‴-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakisbenzoate tetrafluoroborate
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 7, Issue 9, September 2006, Pages 673–677
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us