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Catalytic decomposition of hydrazine on iron nitride catalysts

Paper ID Volume ID Publish Year Pages File Format Full-Text
52738 46883 2006 5 PDF Available
Title
Catalytic decomposition of hydrazine on iron nitride catalysts
Abstract

A series of iron nitride catalysts were prepared by a temperature-programmed reaction method and evaluated in a microreactor for hydrazine decomposition. The catalytic activity of iron nitride is apparently higher than those of iron oxide catalysts. The noble-metal-like characteristics of the nitrides might be responsible for the high catalytic activity. The iron nitride catalysts prepared at different temperatures have different bulk structures, whereas they have similar specific catalytic activity per m2. The iron nitrides with larger surface areas and smaller particle sizes produced higher catalytic activities and H2 selectivities at high temperatures. The iron nitride catalysts were also compared with the molybdenum nitride and niobium nitride, and the catalytic activities for hydrazine decomposition increase in the order of NbN ≪ FeNx ∼ γ-Mo2N.

Keywords
Hydrazine decomposition; Iron nitride catalyst; Microreactor
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Catalytic decomposition of hydrazine on iron nitride catalysts
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 7, Issue 3, March 2006, Pages 187–191
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
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