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The oxidation of olefins by t-butyl hydrogen peroxide to prepare 1,2-diols over metal oxide catalysts

Paper ID Volume ID Publish Year Pages File Format Full-Text
52765 46886 2009 5 PDF Available
Title
The oxidation of olefins by t-butyl hydrogen peroxide to prepare 1,2-diols over metal oxide catalysts
Abstract

Trans-1,2-cyclohexanediol was synthesized from the oxidation of cyclohexene. The t-butyl hydrogen peroxide (TBHP) was used as oxidant. High cyclohexene conversion (93%) with high 1,2-cyclohexanediol selectivity (98.2%) was obtained over MoO3. Among the tested metal oxide catalysts MoO3, VO5, Nb2O5, Cr2O3, and WO3, MoO3 was found to be the most active catalyst for the oxidation of cyclo-olefins to prepare 1,2-diols. Except cyclohexene oxidation, MoO3 was also found to be active for the oxidation of other cyclo-olefins.

Keywords
Olefin oxidation; 1,2-Diols; MoO3 catalyst; t-Butyl hydrogen peroxide
First Page Preview
The oxidation of olefins by t-butyl hydrogen peroxide to prepare 1,2-diols over metal oxide catalysts
Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 10, Issue 9, 25 April 2009, Pages 1279–1283
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis