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FT-IR characterization of [bupy]BF4-MCl3 (M = Al, Fe) ionic liquids using new molecular probe and their alkylation performance

Paper ID Volume ID Publish Year Pages File Format Full-Text
52772 46886 2009 3 PDF Available
Title
FT-IR characterization of [bupy]BF4-MCl3 (M = Al, Fe) ionic liquids using new molecular probe and their alkylation performance
Abstract

In the present work, the acidity of [bupy]BF4-MCl3 (M = Al, Fe) ionic liquids was characterized by means of FT-IR technique using acetonitrile as molecular probe. The results show that only Lewis acidity is present in these ionic liquids and the acidity strength of [bupy]BF4-AlCl3 is stronger than [bupy]BF4-FeCl3. In the alkylation reaction of toluene and 1,3-pentadiene to produce pentenyltoluene, the catalytic activities of these ionic liquids catalysts can be correlated with their Lewis acidity.

Keywords
Ionic liquid; FT-IR; Alkylation; Acidity
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FT-IR characterization of [bupy]BF4-MCl3 (M = Al, Fe) ionic liquids using new molecular probe and their alkylation performance
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 10, Issue 9, 25 April 2009, Pages 1310–1312
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
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