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Selective oxidation of ethylbenzene by a biomimetic combination: Hemin and N-hydroxyphthalimide (NHPI)

Paper ID Volume ID Publish Year Pages File Format Full-Text
52789 46887 2007 4 PDF Available
Title
Selective oxidation of ethylbenzene by a biomimetic combination: Hemin and N-hydroxyphthalimide (NHPI)
Abstract

A biomimetic catalytic system consisting of hemin and N-hydroxyphthalimide (NHPI) for the selective oxidation of ethylbenzene with dioxygen is reported. 90.32% conversion of ethylbenzene with 94.30% selectivity for acetophenone (AcPO) can be obtained at 100 °C under 0.3 MPa O2 for 9 h. Hemin can efficiently decompose in situ formed 1-phenylethyl hydroperoxide (PEHP) with AcPO as the main product.

Keywords
Ethylbenzene; Hemin; N-hydroxyphthalimide; Oxidation
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Selective oxidation of ethylbenzene by a biomimetic combination: Hemin and N-hydroxyphthalimide (NHPI)
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 8, Issue 1, January 2007, Pages 27–30
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us