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Oxidation of cyclohexane promoted by [Fe(III)(Salen)Cl] and [Mn(III)(Salen)Cl]

Paper ID Volume ID Publish Year Pages File Format Full-Text
52797 46887 2007 4 PDF Available
Title
Oxidation of cyclohexane promoted by [Fe(III)(Salen)Cl] and [Mn(III)(Salen)Cl]
Abstract

Salen complexes of iron(III) and manganese(III) were synthesized and employed as catalysts in the oxidation of cyclohexane, using hydrogen peroxide and tert–butylhydroperoxide. The reactions were carried out in acetonitrile at room temperature. The catalysts were characterized by infrared and Mössbauer spectroscopy, elemental analysis, conductivity and cyclic voltammetry. Conversions up to 10.2% (4.2% and 6.0% yields for cyclohexanol and cyclohexanone, respectively) were obtained for the system [Fe(III)(Salen)Cl]/tBuOOH.

Keywords
Cyclohexane; Oxidation; Salen; Biomimetic catalyst
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Oxidation of cyclohexane promoted by [Fe(III)(Salen)Cl] and [Mn(III)(Salen)Cl]
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 8, Issue 1, January 2007, Pages 69–72
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
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Full-text PDF Download
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