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ZrCl4-catalyzed aza-Michael addition of carbamates to enones: Synthesis of Cbz-protected β-amino ketones

Paper ID Volume ID Publish Year Pages File Format Full-Text
52861 46890 2007 3 PDF Available
Title
ZrCl4-catalyzed aza-Michael addition of carbamates to enones: Synthesis of Cbz-protected β-amino ketones
Abstract

The reaction of α,β-unsaturated ketones with benzyl carbamate and 2-oxazolidinone was effectively promoted by a catalytic amount of zirconium (IV) chloride to produce the corresponding β-amino ketones.

Keywords
α,β-Unsaturated ketones; Carbamates; Michael addition; Zirconium (IV) chloride
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ZrCl4-catalyzed aza-Michael addition of carbamates to enones: Synthesis of Cbz-protected β-amino ketones
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 8, Issue 3, March 2007, Pages 434–436
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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