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Clean synthesis of adipic acid catalyzed by complexes derived from heteropoly acid and glycine

Paper ID Volume ID Publish Year Pages File Format Full-Text
52931 46892 2009 4 PDF Available
Title
Clean synthesis of adipic acid catalyzed by complexes derived from heteropoly acid and glycine
Abstract

Adipic acid was synthesized from cyclohexene and hydrogen peroxide in high yield of 95.1% and excellent selectivity of 99.8% with heteropoly complexes as catalysts. The heteropoly complexes were prepared from heteropoly acids and glycine, and characterized by TG-DSC, elementary analysis, gravimetry and IR spectroscopy. The catalysts prepared showed more efficient than the corresponding heteropoly acids in the synthesis of adipic acid, and W-based heteropoly compounds exhibited higher activities than Mo-based heteropoly compounds.

Keywords
Adipic acid; Hydrogen peroxide; Catalytic oxidation; Clean synthesis; Heteropoly compound
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Clean synthesis of adipic acid catalyzed by complexes derived from heteropoly acid and glycine
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 10, Issue 5, 25 January 2009, Pages 464–467
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us