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Lewis acid-catalyzed Beckmann rearrangement of ketoximes in ionic liquids

Paper ID Volume ID Publish Year Pages File Format Full-Text
52962 46892 2009 6 PDF Available
Title
Lewis acid-catalyzed Beckmann rearrangement of ketoximes in ionic liquids
Abstract

The Beckmann rearrangement of five ketoximes was done in 17 different ionic liquids by using four Lewis acids. The effect of the type of cation and the type of anion in the ionic liquid on the rate of the rearrangement reaction and product composition is compared and discussed. The effects of the hydrophobicity and the hydrogen bonding ability of ionic liquids on the rearrangement of ketoximes were investigated, as well as the catalytical activity of the Lewis acids.

Keywords
Ionic liquids; Beckmann rearrangement; Lewis acids
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Lewis acid-catalyzed Beckmann rearrangement of ketoximes in ionic liquids
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 10, Issue 5, 25 January 2009, Pages 614–619
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us