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Hydrogenolysis of O-protected hydroxyoxetanes over palladium: An efficient method for a one-step ring opening and detritylation reaction

Paper ID Volume ID Publish Year Pages File Format Full-Text
52967 46892 2009 5 PDF Available
Title
Hydrogenolysis of O-protected hydroxyoxetanes over palladium: An efficient method for a one-step ring opening and detritylation reaction
Abstract

An efficient method for the palladium mediated hydrogenation of an optically active, O-protected hydroxyoxetane derivative has been developed. Using appropriate solvents, in a one-step reaction, optically active 1,4-diol was formed over a Pd/C catalyst, during hydrogenolytic ring opening and detritylation reactions.

Keywords
Chiral oxetanes; Optically active 1,4-diols; Hydrogenolysis; Catalytic hydrogenation; Palladium; Solvent effects
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Hydrogenolysis of O-protected hydroxyoxetanes over palladium: An efficient method for a one-step ring opening and detritylation reaction
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 10, Issue 5, 25 January 2009, Pages 635–639
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us