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Synthesis of (−)-hinokinin by oxidation of (−)-cubebin catalyzed by biomimetic metalloporphyrin catalytic systems

Paper ID Volume ID Publish Year Pages File Format Full-Text
52974 46892 2009 4 PDF Available
Title
Synthesis of (−)-hinokinin by oxidation of (−)-cubebin catalyzed by biomimetic metalloporphyrin catalytic systems
Abstract

A catalytic system consisting of iron tetraphenylporphyrin supported on an alumina matrix for oxidation of (−)-cubebin with iodosylbenzene or hydrogen peroxide is reported. Conversion of (−)-cubebin is very efficient (100%) with 100% selectivity producing only (−)-hinokinin when iodosylbenzene is used as the oxidant and 70% conversion with 100% selectivity when hydrogen peroxide is the oxidant at room temperature under atmospheric pressure.

Keywords
Biomimetic catalysis; Fe-porphyrin; (−)-Hinokinin; (−)-Cubebin; Oxidation
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Synthesis of (−)-hinokinin by oxidation of (−)-cubebin catalyzed by biomimetic metalloporphyrin catalytic systems
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 10, Issue 5, 25 January 2009, Pages 669–672
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us