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Chiral iron(III)-salen-catalyzed oxidation of hydrocarbons

Paper ID Volume ID Publish Year Pages File Format Full-Text
52982 46892 2009 4 PDF Available
Title
Chiral iron(III)-salen-catalyzed oxidation of hydrocarbons
Abstract

A group of chiral iron(III)-salen complexes (1–4) were employed as catalysts in the oxidation of a variety of alkenes at room temperature using pentafluoroiodosylbenzene as terminal oxidant. The reactions were carried out in both acetonitrile and dichloromethane. Iron(III)-salen-catalyzed oxygenation reactions were found to be dependent upon the reaction medium. At room temperature, oxygenation of cyclohexane has also been achieved up to 23% (13% and 10% yields for cyclohexanol and cyclohexanone, respectively) in acetonitrile medium.

Keywords
Fe(III)-salen; Oxygenation; Catalysis; Iodosylarene
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Chiral iron(III)-salen-catalyzed oxidation of hydrocarbons
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 10, Issue 5, 25 January 2009, Pages 708–711
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
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Full-text PDF Download
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