fulltext.study @t Gmail

Effective heterogenization and catalytic use of active C5H5 NiLX complex for the hydrosilylation

Paper ID Volume ID Publish Year Pages File Format Full-Text
53078 46901 2008 6 PDF Available
Title
Effective heterogenization and catalytic use of active C5H5 NiLX complex for the hydrosilylation
Abstract

An effective route was first developed to heterogenize active C5H5NiLX complex for the preparation of the solid catalyst . The attachment of the nickel complex onto the polymer was carefully characterized by IR, solid diffuse reflectance UV–vis, 31P CP MASNMR spectra and ICP-OES elemental analysis, which proved that the present route was relatively simple and effective for the immobilization of active centers, and that the materials used was considerably cheap. Thus-prepared solid catalyst showed high activity, selectivity and an excellent recyclability for the hydrosilylation of alkenes with trichlorosilane at mild conditions, outstandingly overcoming the problem of homogeneous system. This is a key success to provide a new methodology for heterogenizing active homogeneous components.

Keywords
Polystyrene beads; Immobilization; Heterogeneous solid nickel complex catalyst; Hydrosilylation
First Page Preview
Effective heterogenization and catalytic use of active C5H5 NiLX complex for the hydrosilylation
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us
Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 9, Issue 8, 20 April 2008, Pages 1793–1798
Authors
, , , , , ,
Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us