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Baeyer–Villiger oxidation of ketones with hydrogen peroxide catalyzed by cellulose-supported dendritic Sn complexes

Paper ID Volume ID Publish Year Pages File Format Full-Text
53087 46907 2007 7 PDF Available
Title
Baeyer–Villiger oxidation of ketones with hydrogen peroxide catalyzed by cellulose-supported dendritic Sn complexes
Abstract

Cellulose supported dendritic Sn complexes were prepared by solid phase synthetic methodology. A series of cycloketones and acyclic ketones including 2-andamantanone, cyclohexanone, 4-methylcyclohexanone, 4-tert-butylcyclohexanone, 3-methyl-2-pentanone, 4-methyl-2-pentanone and cyclopentanone were oxidized by hydrogen peroxide in a reaction catalyzed by cellulose-supported dendritic Sn complexes, affording the corresponding lactones or esters with the conversion of 70–99% and the product selectivity of 100%. The catalysts can be recycled for several times without any significant decline in catalytic activity.

Keywords
Baeyer–Villiger oxidation; Cellulose-supported dendrimer; Hydrogen peroxide; Solid phase synthesis
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Baeyer–Villiger oxidation of ketones with hydrogen peroxide catalyzed by cellulose-supported dendritic Sn complexes
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 8, Issue 8, August 2007, Pages 1202–1208
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
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