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Ruthenium-catalyzed cross-coupling reactions between ketones and primary amines

Paper ID Volume ID Publish Year Pages File Format Full-Text
53148 46915 2006 3 PDF Available
Title
Ruthenium-catalyzed cross-coupling reactions between ketones and primary amines
Abstract

Ketones react with primary amines in dioxane at 180 °C in the presence of a catalytic amount of a ruthenium catalyst to give the corresponding α-alkylated ketones in moderate to good yields. With alkyl(methyl) ketones, the alkylation takes place exclusively at less-hindered methyl position over α-methylene.

Keywords
α-Alkylation; Cross-coupling; Ketones; Primary amines; Ruthenium catalyst
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Ruthenium-catalyzed cross-coupling reactions between ketones and primary amines
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 7, Issue 12, December 2006, Pages 1012–1014
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
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Price was $35.95
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Price after discount Only $4.95
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