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Synthesis of dimethyl carbonate from urea and methanol over solid base catalysts

Paper ID Volume ID Publish Year Pages File Format Full-Text
53179 46921 2006 5 PDF Available
Title
Synthesis of dimethyl carbonate from urea and methanol over solid base catalysts
Abstract

The synthesis of dimethyl carbonate (DMC) from urea and methanol was found to take place over solid base catalysts. In the first step, the intermediate MC was produced with high yield by urea monomethanolysis and then MC further converted to DMC by reacting with methanol, which was the key step. Solid bases were found to be effective catalysts for the second step and their basic properties were measured by CO2-TPD. The function of basic catalysts could be attributed to the activation of CH3OH via the abstraction of Hδ+ by base sites.

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Synthesis of dimethyl carbonate from urea and methanol over solid base catalysts
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 7, Issue 1, January 2006, Pages 6–10
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
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