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Effect of valence of copper in La2−xThxCuO4 on NO decomposition reaction

Paper ID Volume ID Publish Year Pages File Format Full-Text
53183 46921 2006 4 PDF Available
Title
Effect of valence of copper in La2−xThxCuO4 on NO decomposition reaction
Abstract

NO decomposition reaction was investigated over La2−xThxCuO4, in which the valence of copper was controlled by Th substitution and was characterized by XPS measurement. A close correlation between the valence of copper and the activity was observed. The activity increased with the decrease of the average oxidation number of copper, and increased with the increase of Cu+ content, suggesting that the transition metal with low valence (Cu+) is active for the reaction in the present cases.

Keywords
Perovskite-like oxides; La2−xThxCuO4; XPS; NO decomposition
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Effect of valence of copper in La2−xThxCuO4 on NO decomposition reaction
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Communications - Volume 7, Issue 1, January 2006, Pages 29–32
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
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