fulltext.study @t Gmail

Selective cyclohexane oxidation catalyzed by manganese porphyrins and co-catalysts

Paper ID Volume ID Publish Year Pages File Format Full-Text
53314 46962 2016 6 PDF Available
Title
Selective cyclohexane oxidation catalyzed by manganese porphyrins and co-catalysts
Abstract

•Catalytic activity of co-catalysts is found to be closely related to the polarity.•High selectivity of products in the cyclohexane oxidation is achieved.•We report a new approach for preparing glutaric acid.

Several polar molecules, such as alcohols, ketones, esters and acids, were used as co-catalysts for the cyclohexane oxidation catalyzed by manganese porphyrins, and the catalytic activity was found to be closely related to polarity of co-catalysts. The results indicated that the total selectivity of products was as high as 96.3% and glutaric acid selectivity was up to 50.9%. Thus, the proposed method provides a new approach for preparing glutaric acid.

Graphical abstractFigure optionsDownload full-size imageDownload high-quality image (78 K)Download as PowerPoint slide

Keywords
Cyclohexane; Selective oxidation; Manganese porphyrins; Co-catalysts; Organic acids
First Page Preview
Selective cyclohexane oxidation catalyzed by manganese porphyrins and co-catalysts
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us
Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Today - Volume 264, 15 April 2016, Pages 185–190
Authors
, , , ,
Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us