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Biomass to value added chemicals: Isomerisation of β-pinene oxide over supported ionic liquid catalysts (SILCAs) containing Lewis acids

Paper ID Volume ID Publish Year Pages File Format Full-Text
53479 46971 2015 4 PDF Available
Title
Biomass to value added chemicals: Isomerisation of β-pinene oxide over supported ionic liquid catalysts (SILCAs) containing Lewis acids
Abstract

•Supported ionic liquid catalysts (SILCAs) are modified with Lewis acidic species.•Catalysts are applied in β-pinene oxide isomerisation reactions.•SILCAs are efficient catalysts for the transformation of β-pinene oxide into myrtanal.

The isomerisation of β-pinene oxide was studied over supported ionic liquid catalysts (SILCAs) consisting of Lewis acids in immobilized ionic liquid. SILCAs were demonstrated as efficient catalysts for the transformation of β-pinene oxide to myrtanal with the product distribution and activity being dependent on the nature of the ionic liquid and Lewis acid strength of catalytic species. With the catalyst ZnCl2/[N(3-OH-Pr)Py][NTf2]/ACC, the highest myrtanal molar yield obtained was 68%.

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Keywords
Isomerisation; Ionic liquids; SILCA
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Biomass to value added chemicals: Isomerisation of β-pinene oxide over supported ionic liquid catalysts (SILCAs) containing Lewis acids
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Today - Volume 257, Part 2, 15 November 2015, Pages 318–321
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
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