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Synthesis of three-dimensionally ordered macroporous Al–Ce mixed oxide catalysts with high catalytic activity and stability for diesel soot combustion

Paper ID Volume ID Publish Year Pages File Format Full-Text
53624 46977 2015 11 PDF Available
Title
Synthesis of three-dimensionally ordered macroporous Al–Ce mixed oxide catalysts with high catalytic activity and stability for diesel soot combustion
Abstract

•3DOM Al–Ce mixed oxide catalysts were successfully synthesized by the CCT method.•3DOM Al–Ce mixed oxide catalysts show good catalytic performance for soot combustion.•The macropores effect plays an important role in soot combustion reaction.•The Al dopant can improve the thermal and catalytic stability of Ce-based catalysts.

A series of three-dimensionally ordered macroporous (3DOM) Al–Ce mixed oxide catalysts were prepared by the colloidal crystal templating method. The obtained catalysts were characterized by means of XRD, SEM, BET, H2-TPR, and Raman spectroscopy. The effects of an Al/Ce ratio on the phase structure and catalytic performances were investigated. Al–Ce mixed oxide catalysts could form solid solutions with moderate aluminum content. 3DOM samples showed higher catalytic activity for soot combustion than corresponding disordered macroporous (DM) ones due to enhanced contact efficiency between the soot and the catalyst. 3DOM mixed oxide catalyst with aluminum to cerium ratio of 3:7 shows the highest catalytic activity for soot combustion, in which the values of T10, T50, and T90 are 297, 384, and 427 °C, respectively. The doping of Al into CeO2 catalysts can enhance the catalytic stability of the catalyst. After 6-cycle runs, the T50 value of 3DOM samples with alumina:cerium (3:7) and alumina:cerium (6:4) have no significant change. Furthermore, the effect of thermal treatments on the catalytic properties for soot combustion was also studied. Compared with 3DOM bare CeO2, 3DOM Al–Ce mixed oxide catalysts exhibited higher thermal stability because aluminum can prevent cerium particles from agglomeration.

Graphical abstractA series of 3DOM Al–Ce mixed oxide catalysts were successfully prepared by the colloidal crystal templating method. Compared with 3DOM bare CeO2, 3DOM Al–Ce mixed oxide catalysts exhibited higher thermal and catalytic stability.Figure optionsDownload full-size imageDownload high-quality image (209 K)Download as PowerPoint slide

Keywords
Three-dimensionally ordered macroporous materials; Al–Ce mixed oxide catalysts; Soot combustion; Stability
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Synthesis of three-dimensionally ordered macroporous Al–Ce mixed oxide catalysts with high catalytic activity and stability for diesel soot combustion
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Today - Volume 258, Part 2, 1 December 2015, Pages 487–497
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us