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Catalytic role of β-Mo2C in DRM catalysts that contain Ni and Mo

Paper ID Volume ID Publish Year Pages File Format Full-Text
53646 46977 2015 8 PDF Available
Title
Catalytic role of β-Mo2C in DRM catalysts that contain Ni and Mo
Abstract

•The Mo-containing catalysts are superior to Ni/La2O3 in catalytic stability in DRM reaction.•β-Mo2C acts as an important intermediate to participate the reaction.•Better resistance to carbon deposition obtained over Mo containing catalysts.

The Mo-containing Ni-Mo2C/La2O3 catalyst was prepared and its catalytic performance compared with that of Ni/La2O3 for the dry reforming of methane (DRM). The former shows better catalytic stability, and there is the formation of Ni and La2MoO6 and a small amount of β-Mo2C. By comparing Ni-Mo2C/La2O3 with the Ni/La2MoO6 and NiMoOx/La2O3 catalysts that are similar in Ni and Mo loadings, we clarify the catalytic role of β-Mo2C in DRM reaction.

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Keywords
Methane; Carbon dioxide; Molybdenum carbide; Nickel
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Catalytic role of β-Mo2C in DRM catalysts that contain Ni and Mo
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Today - Volume 258, Part 2, 1 December 2015, Pages 676–683
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
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Price after discount Only $4.95
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