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Aqueous phase catalytic hydroformylation reactions of alkenes

Paper ID Volume ID Publish Year Pages File Format Full-Text
54014 46993 2015 12 PDF Available
Title
Aqueous phase catalytic hydroformylation reactions of alkenes
Abstract

•Overview of recent developments for aqueous phase hydroformylation of alkenes.•Water soluble ligands developments for rhodium/cobalt catalyzed hydroformylation.•Use on surfactants, mass transfer additives (cyclodextrins).•Amphiphilic phosphine based ligands.•Use of aqueous phase hydroformylation for synthesis of fine chemicals.

The present article provides an overview of the recent developments in the area of aqueous phase hydroformylation of alkenes. The commercial application of aqueous phase hydroformylation reaction is restricted to the lower carbon chain alkenes due to the solubility and mass transfer limitations of the higher carbon chain alkenes in aqueous phase. The approaches which have been developed to improve the solubility of higher carbon chain length alkenes for aqueous phase hydroformylation reaction are emphasized in this article.

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Keywords
Biphasic hydroformylation; Aqueous phase; Alkene; Aldehyde; Surfactant; Cyclodextrins
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Today - Volume 247, 1 June 2015, Pages 70–81
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us