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Mechanism of propene poisoning on Cu-SSZ-13 catalysts for SCR of NOx with NH3

Paper ID Volume ID Publish Year Pages File Format Full-Text
54034 46994 2015 6 PDF Available
Title
Mechanism of propene poisoning on Cu-SSZ-13 catalysts for SCR of NOx with NH3
Abstract

•Catalytic activity of Cu-SSZ-13 is obviously inhibited by C3H6 in the whole temperature ranges.•Competitive adsorption between NOx and C3H6 is the main factor for Cu-SSZ-13 deactivation in low temperature ranges.•Coke depositions contribute for Cu-SSZ-13 deactivation around 350 °C.•Cu-SSZ-13 catalysts can be regenerated above 450 °C in rich oxygen.

Application of Cu-exchanged chabazite catalysts for Urea-SCR of NOx in diesel engines is limited to some extent by catalyst deactivation with hydrocarbons (HCs). In this work, catalytic activity of commercial Cu-SSZ-13 catalysts with or without propene for selective catalytic reduction of NOx with ammonia (NH3-SCR) was tested, and results showed that the DeNOx activity was obviously inhibited in the whole temperatures, especially in medium temperatures. Furthermore, BET, NH3-TPD, NOx-TPD, and in situ DRIFTS were employed to elaborate the propene poisoning effects on Cu-SSZ-13 catalysts. In the low temperature ranges, the competitive adsorption process between NOx and C3H6 contributed to the deactivation of Cu-SSZ-13 catalysts. The presence of propene would inhibit the NOx adsorption and activation on the catalyst surface. In the medium temperature ranges, coke depositions were very critical for the deactivation of Cu-SSZ-13 catalysts. The active copper sites would be covered by the coke depositions, while the chabazite zeolite pores were also blocked by coke depositions. At higher temperatures above 450 °C, coke could be quickly removed and the catalysts could be regenerated in the presence of rich oxygen.

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Keywords
Diesel emission control; Chabazite zeolite; C3H6 effect; Competitive adsorption; Coke
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Mechanism of propene poisoning on Cu-SSZ-13 catalysts for SCR of NOx with NH3
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Today - Volume 245, 1 May 2015, Pages 16–21
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us