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The use of a natural Mexican zeolite as support of NiMoW sulphide hydrotreating catalysts

Paper ID Volume ID Publish Year Pages File Format Full-Text
54411 47008 2014 9 PDF Available
Title
The use of a natural Mexican zeolite as support of NiMoW sulphide hydrotreating catalysts
Abstract

•Naturally occurring zeolite supported NiMoW catalysts were tested in hydrodesulfurization of dibenzothiophene.•The best catalyst was synthesized from ammonium thiosalts of Mo and W.•The use of tetraalkylammonium thiometalates precursors decrease the HDS activity.•The density of active phases on the support surface influenced on the HDS activity

In order to examine the influence of type of metal precursor on the hydrodesulfurization (HDS) activity of synthetized samples, a series of ternary Ni–Mo–W catalysts supported on a natural Mexican zeolite (clinoptilolite) were prepared by sequential wet impregnation of the zeolite support with different thiosalts of W and Mo, and Ni(NO3)2·6H2O. The synthetized samples were characterized by N2 adsorption–desorption isotherms at −196 °C, X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX/SEM), high-resolution transmission electron microscopy (HRTEM) and X-ray photoelectron spectroscopy (XPS) techniques. The catalysts activity was evaluated in the HDS of dibenzothiophene (DBT) reaction performed in a batch reactor at 350 °C and 3.1 MPa of total hydrogen pressure. The activity tests demonstrated that the best catalyst was the NiMoW-H/zeo sample synthesized from ammonium thiosalts. The use of tetraalkylammonium thiometalates as metal precursors led to the decrease in the HDS activity. The most active catalyst in the HDS of DBT reaction showed the largest density of active phases on the support surface determined from HRTEM measurements.

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Keywords
Hydrodesulphurization; Dibenzothiophene; Zeolite; Clinoptilolite
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The use of a natural Mexican zeolite as support of NiMoW sulphide hydrotreating catalysts
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Today - Volumes 220–222, March 2014, Pages 301–309
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us