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Three different types of heterocycle of nitrogen-containing alkaline ionic liquids treatment of acid oil to remove naphthenic acids

Paper ID Volume ID Publish Year Pages File Format Full-Text
54824 47027 2013 6 PDF Available
Title
Three different types of heterocycle of nitrogen-containing alkaline ionic liquids treatment of acid oil to remove naphthenic acids
Abstract

Ionic liquids had enormous potential for industrial use as environmental friendly chemicals. A green and effective deacidification method was found based on ionic liquids. N-alkylpyridinium bromide ([APy]Br), 1-alkyl-3-methylimidazolium bromide ([AMIm]Br) and 1-alkyl-3-methylimidazolium imidazolide ([AMIm]Im) were used to remove naphthenic acids from acid oil. The performance of deacidification followed the order [APy]Br < [AMIm]Br < [AMIm]Im. The stronger alkalinity of ionic liquids was, the higher deacidification would be. The growth of alkyl chain length was also beneficial to get high deacidification. The deacidification mechanism was that liquid clathrate could form due to interaction between the ionic liquids and π-bond in naphthenic acids through π–π interaction. When the reagent/oil ratio of [OMIm]Im (1-octyl-3-methylimidazolium imidazolide)/oil was 0.008, the deacidification rate could be reached 100%. The preliminary results reveal that the process consumes less energy, saves time and produces less pollution to environment.

Graphical abstractFigure optionsDownload full-size imageDownload high-quality image (113 K)Download as PowerPoint slideHighlights► The stronger alkalinity of ionic liquids was, the higher deacidification would be. ► The growth of alkyl chain length was beneficial to get high deacidification. ► The optimal reaction temperature was 323 K. ► [OMIm]Im was the optimized ionic liquid to remove naphthenic acid. ► Due to π–π interaction, naphthenic acid could be removed effectively by ILs.

Keywords
Ionic liquids; Naphthenic acid; Deacidification; 1-Alkyl-3-methylimidazolium bromide; N-alkylpyridinium bromide; 1-Alkyl-3-methylimidazolium imidazolide
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Three different types of heterocycle of nitrogen-containing alkaline ionic liquids treatment of acid oil to remove naphthenic acids
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Today - Volume 212, 1 September 2013, Pages 180–185
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us