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Few-layer graphene supporting palladium nanoparticles with a fully accessible effective surface for liquid-phase hydrogenation reaction

Paper ID Volume ID Publish Year Pages File Format Full-Text
55365 47049 2012 6 PDF Available
Title
Few-layer graphene supporting palladium nanoparticles with a fully accessible effective surface for liquid-phase hydrogenation reaction
Abstract

Palladium nanoparticles (NPs) dispersed on a few-layer graphene (FLG) surface were investigated as a catalyst for the liquid-phase selective hydrogenation of the CC bond. The Pd/FLG catalyst exhibits a high hydrogenation activity compared to those obtained on the 1D support, i.e. carbon nanotubes. The high hydrogenation activity and CC bond hydrogenation selectivity was attributed to the 2D morphology of the support with an extremely high accessible surface for reactant access and for desorption of the intermediate products before secondary hydrogenation.

Graphical abstract.Figure optionsDownload full-size imageDownload high-quality image (255 K)Download as PowerPoint slideHighlights► Palladium supported on Few Layer Graphene as a new cactalyst. ► High dispersion of palladium nanoparticles on the Few Layer Graphene. ► High hydrogenantion activity and CC bond hydrogenation selectivity. ► High accessibility for the reactant to the active site.

Keywords
Graphene; Palladium; Hydrogenation; Catalysis; Cinnamaldehyde
First Page Preview
Few-layer graphene supporting palladium nanoparticles with a fully accessible effective surface for liquid-phase hydrogenation reaction
Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Today - Volume 189, Issue 1, 30 July 2012, Pages 77–82
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis