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Improving effect of Fe additive on the catalytic stability of Mo/HZSM-5 in the methane dehydroaromatization

Paper ID Volume ID Publish Year Pages File Format Full-Text
55499 47056 2012 6 PDF Available
Title
Improving effect of Fe additive on the catalytic stability of Mo/HZSM-5 in the methane dehydroaromatization
Abstract

The promotional effects of eight kinds of transition metal additives (0.5 wt%) on the activity and stability of 5 wt%Mo/HZSM-5 were screened at 1073 K and 10,000 mL/g/h in a continuous CH4 feed mode. Only Fe was observed to improve the activity stability. Subsequently, confirmation tests were performed with other three Fe-modified catalysts containing 0.3, 1.0 and 2.0 wt% of Fe in the same continuous operation mode and also with the 0.5 wt%Fe–5 wt%Mo/HZSM-5 under periodic CH4–H2 switch operation for 1650 min. It was confirmed that Fe indeed enhanced the stability of Mo/HZSM-5 catalyst. Then, TPO, TG and BET measurements and SEM observations were performed for almost all spent samples to gain insight into the promotion mechanism of Fe additive. The results revealed that over short time frames in the continuous CH4 feed mode the formation of Fe-induced carbon nanotubes is the origin of its promotional effect, while under the long-term periodic CH4–H2 switch operation the catalytic involvement of Fe in the surface coke removal during the H2 flow periods is the main cause of Fe-modified catalyst being much more stable than the unmodified Mo/HZSM-5 catalyst

Graphical abstractFe promoter improves significantly the catalytic stability of Mo/HZSM-5 in the non-oxidative dehydroaromatization at severe condition.Figure optionsDownload full-size imageDownload high-quality image (165 K)Download as PowerPoint slideHighlights► Screening of transition metal promoters at the severe condition of 1073 K and 10,000 mL/g/h. ► Long term periodic CH4–H2 switch tests to confirm Fe's promotional effect. ► SEM observation and TPO, TG and BET measurements to study the promotion mechanism. ► Formation of Fe-induced carbon nanotubes and Fe-catalyzed coke removal are related to the promotional effect.

Keywords
Methane dehydroaromatization; Mo/HZSM-5; Metal additives; Carbon nanotube
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Improving effect of Fe additive on the catalytic stability of Mo/HZSM-5 in the methane dehydroaromatization
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Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Today - Volume 185, Issue 1, 20 May 2012, Pages 41–46
Authors
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Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us