fulltext.study @t Gmail

Use of probe molecules for Fischer–Tropsch mechanistic investigations: A short review

Paper ID Volume ID Publish Year Pages File Format Full-Text
55652 47060 2011 5 PDF Available
Title
Use of probe molecules for Fischer–Tropsch mechanistic investigations: A short review
Abstract

The Fischer–Tropsch synthesis (FTS) mechanism is still not fully understood and the product distribution does not generally follow a typical Anderson–Schulz–Flory (ASF) distribution. In order to improve the understanding of the reaction mechanism and in an attempt to explain the deviations observed from the ASF distribution, additives such as olefins, alcohols, carbon dioxide, water, and isotope markers, have been used in the FTS. This paper briefly reviews the effect of additives and their impact on the FTS mechanism.

Graphical abstractSecondary olefin reactions in Fischer Tropsch synthesis (H. Schulz, M. Claeys, Applied Catalysis A: General 186 (1999) 71).Figure optionsDownload full-size imageDownload high-quality image (99 K)Download as PowerPoint slideHighlights► The effect of additives on the mechanism of FTS is reviewed. ► Additives initiate chain growth, but are not incorporated in the growing chain. ► Selectivity of FTS could be based on active site modification by syngas additives.

Keywords
Fischer Tropsch; Mechanism; Gas to liquids; Probe molecules; ASF distribution; Additives
First Page Preview
Use of probe molecules for Fischer–Tropsch mechanistic investigations: A short review
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us
Publisher
Database: Elsevier - ScienceDirect
Journal: Catalysis Today - Volume 178, Issue 1, 15 December 2011, Pages 137–141
Authors
, ,
Subjects
Physical Sciences and Engineering Chemical Engineering Catalysis
Get Full-Text Now
Don't Miss Today's Special Offer
Price was $35.95
You save - $31
Price after discount Only $4.95
100% Money Back Guarantee
Full-text PDF Download
Online Support
Any Questions? feel free to contact us